Preparation of a semantically wrong chemical species: A superstable radical persistent under 100% F2 atmosphere.
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Accession number;02A0620406
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| Title;Preparation of a semantically wrong chemical species: A superstable radical persistent under 100% F2 atmosphere. |
| Author;
ONO T
(Inst. Advanced Ind. Sci. And Technol., Nagoya, Jpn)
HAYASHI E
(Inst. Advanced Ind. Sci. And Technol., Nagoya, Jpn)
NISHIDA M
(Inst. Advanced Ind. Sci. And Technol., Nagoya, Jpn)
FUKAYA H
(Inst. Advanced Ind. Sci. And Technol., Nagoya, Jpn)
TORIYAMA K
(Inst. Advanced Ind. Sci. And Technol., Nagoya, Jpn)
OKAZAKI M
(Inst. Advanced Ind. Sci. And Technol., Nagoya, Jpn)
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Journal Title;Fusso Kagaku Toronkai Koen Yoshishu
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Journal Code:F0135B
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ISSN:
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VOL.25th;NO.;PAGE.18-19(2001)
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| Figure&Table&Reference; |
| Pub. Country;Japan |
| Language;English |
| Abstract;One of the hexafluoropropene trimers was converted into a highly branched perfluoro-2,4-dimethyl-3-isopropyl-2-pentene in high yield by using trifluoromethyl trimethyl-silane. Direct fluorination of this olefin gave perfluoro-2,4-dimethyl-3-isopropyl-2-pentyl radical in almost quantitative yield. This radical was found to be persistent under 100% F2 atmosphere. The structure of the radical was confirmed by ESR. (author abst.) |
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