A Chemistry of Multicenter Single Proton Hydrogen Bond of Trifluorolactates.

Accession number;02A0620408
Title;A Chemistry of Multicenter Single Proton Hydrogen Bond of Trifluorolactates.
Author; KATAGIRI T (Okayama Univ., Okayama, Jpn) MUKAE M (Okayama Univ., Okayama, Jpn) UNEYAMA K (Okayama Univ., Okayama, Jpn)
Journal Title;Fusso Kagaku Toronkai Koen Yoshishu
Journal Code:F0135B
ISSN:
VOL.25th;NO.;PAGE.22-23(2001)
Figure&Table&Reference;
Pub. Country;Japan
Language;English
Abstract;An X-ray crystallographic analysis of optically pure isopropyl trifluorolactate suggested possible seven centered hydrogen bondings with chirality; the hydroxy group was surrounded by three intra- and three intermolecular proton acceptors within reasonable hydrogen bonding distances. Crystal engineering method for preparation of subnano size tunnels with this hydrogen bonding system was also achieved. (author abst.)