Mg(0)-Promoted Selective Defluorination of Trifluoromethyl Imines and Synthesis of .BETA.,.BETA.-Difluoroamino Acid Derivatives.
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Accession number;02A0620414
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| Title;Mg(0)-Promoted Selective Defluorination of Trifluoromethyl Imines and Synthesis of .BETA.,.BETA.-Difluoroamino Acid Derivatives. |
| Author;
MAE MASAYUKI
(Okayama Univ., Faculty of Engineering, JPN)
AMII HIDEKI
(Okayama Univ., Faculty of Engineering, JPN)
KATO TSUYOSHI
(Okayama Univ., Faculty of Engineering, JPN)
UNEYAMA KENJI
(Okayama Univ., Faculty of Engineering, JPN)
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Journal Title;Fusso Kagaku Toronkai Koen Yoshishu
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Journal Code:F0135B
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ISSN:
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VOL.25th;NO.;PAGE.39-41(2001)
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| Figure&Table&Reference; |
| Pub. Country;Japan |
| Language;Japanese |
| Abstract;The simple and effective synthetic method of .BETA.,.BETA.-difluoroenamine by magnesium promoted defluorination has been established. Moreover, functionalization at the .BETA.-carbon of the difluoroenanines by not only nucleophiles but also electrophiles and radical species enabled us to synthesize various kinds of .BETA.,.BETA.-difluoroamino acid derivatives. (author abst.) |
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