Hydrostannation and Carbometallation Reactions of Fluorine-Containing Acetylene Derivatives.
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Accession number;02A0620415
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| Title;Hydrostannation and Carbometallation Reactions of Fluorine-Containing Acetylene Derivatives. |
| Author;
NOIRI ATSUSHI
(Kyoto Inst. Technol., Faculty of Engineering and Design, JPN)
KANDA MASASHI
(Kyoto Inst. Technol., Faculty of Engineering and Design, JPN)
KONNO TSUTOMU
(Kyoto Inst. Technol., Faculty of Engineering and Design, JPN)
ISHIHARA TAKASHI
(Kyoto Inst. Technol., Faculty of Engineering and Design, JPN)
YAMANAKA HIROKI
(Kyoto Inst. Technol., Faculty of Engineering and Design, JPN)
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Journal Title;Fusso Kagaku Toronkai Koen Yoshishu
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Journal Code:F0135B
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ISSN:
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VOL.25th;NO.;PAGE.42-44(2001)
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| Figure&Table&Reference; |
| Pub. Country;Japan |
| Language;Japanese |
| Abstract;Treatment of fluorine-containing acetylene derivatives with Bu3SnH in the presence of a catalytic amount of AIBN gave the corresponding vinylstannanes regio- and stereoselectively, which were subjected to the Pd(0)-catalyzed coupling reaction with various halides to afford the tri-substituted alkenes in high yields. Vinylcoppers, produced via the carbocupration reaction of fluorine-containing acetylene derivatives with various cyanocuprates, also reacted with halides to give the corresponding tetra-substituted alkenes in high yields. (author abst.) |
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