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Accession number;02A0620418
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| Title;Development of Novel Synthesis of Cyanofluoroamides Using Cobaltadithiolene Complexes. |
| Author;
SUZUKI SHOKO
(Sophia Univ., Fac. of Sci. and Technol.)
YOKOYAMA YASUO
(Sophia Univ., Fac. of Sci. and Technol.)
KAJITANI MASATSUGU
(Sophia Univ., Fac. of Sci. and Technol.)
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Journal Title;Fusso Kagaku Toronkai Koen Yoshishu
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Journal Code:F0135B
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ISSN:
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VOL.25th;NO.;PAGE.51-53(2001)
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| Figure&Table&Reference; |
| Pub. Country;Japan |
| Language;Japanese |
| Abstract;N,N-diethyl 2-cyano-2-fluoro-2-phenylthio amide was treated with Et3GeNa, and various allyic halides as electrophiles were added to the reaction mixture in the presence of cobaltadithiolene complex having a methyl group, the desired unsaturated cyanofluoroamides were given in good yield. In this presentation we report the results of optimization of reaction conditions and the syntheses of fluorinated amides having various skeleton. (author abst.) |
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