Science Links Japan | Architecture and Application of Self-Assembled Molecular Aggregates of Fluoroalkyl End-Capped Co-oligomers Containing Isocyanato-blocked Segments.

Architecture and Application of Self-Assembled Molecular Aggregates of Fluoroalkyl End-Capped Co-oligomers Containing Isocyanato-blocked Segments.

Accession number;02A0620445

Title;Architecture and Application of Self-Assembled Molecular Aggregates of Fluoroalkyl End-Capped Co-oligomers Containing Isocyanato-blocked Segments.

Author;

Journal Title;Fusso Kagaku Toronkai Koen Yoshishu

Journal Code:F0135B

ISSN:

VOL.25th;NO.;PAGE.118-120(2001)

Figure&Table&Reference;FIG.1, TBL.1, REF.1

Pub. Country;Japan

Language;Japanese

Abstract;A variety of fluoroalkyl end-capped cooligomers containing blocked-isocyanato segments were prepared by the reactions of fluoroalkanoyl peroxides with isocyanatoethyl methacrylate 2-butanone oxime adduct(IEM-BO) and N,N-dimethylacrylamide(DMM). These fluoroalkyl end-capped IEM-BO-DMAA cooligomers were shown to have a good solubility in water and common organic solvents. Interestingly, dynamic light scattering analyses showed that these fluoroalkyl end-capped cooligomers, especially, the longer fluoroalkylated cooligomers are likely to form the molecular aggregates. (author abst.)

Related Articles;