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Accession number;02A0620446
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| Title;Structure and its photochromism of an aggregated ion pair of perfluorosurfactant with azobenzene carboxylate ion. |
| Author;
FURUKAWA TSUYOSHI
(Nagoya Univ., Grad. Sch.)
SASAI RYO
(Nagoya Univ., Grad. Sch.)
HAYASHI EIJI
(National Industrial Res. Inst. Nagoya)
TAKAGI KATSUHIKO
(Nagoya Univ., Grad. Sch.)
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Journal Title;Fusso Kagaku Toronkai Koen Yoshishu
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Journal Code:F0135B
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ISSN:
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VOL.25th;NO.;PAGE.121-123(2001)
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| Figure&Table&Reference;FIG.2, REF.2 |
| Pub. Country;Japan |
| Language;Japanese |
| Abstract;A reaction space has been studied in a casted film of an ion-pair composed of fluorinated ammonium surfactant and azobenzenecarboxylate. In comparing with the hydrogen homologs, the fluorinated ion-pair film provides a reaction space for cis-trans isomerization of the azo chromophore, suggesting that the fluorinated ion-pair forms a packing structure looser than the hydrogen homolog. Polarized spectroscopy reveals that the fluorinated ion-pair forms a monolayer assembly, but the hydrogen homolog affords a bilayer structure of the molecular assembly. (author abst.) |
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