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Accession number;03A0176343
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| Title;Graft Polymerization of Cyclic Compounds on Cellulose Dissolved in Tetrabutylammonium Fluoride / Dimethyl Sulfoxide. |
| Author;
IKEDA I
(Fukui Univ., Fukui, Jpn)
WASHINO K
(Fukui Univ., Fukui, Jpn)
MAEDA Y
(Fukui Univ., Fukui, Jpn)
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Journal Title;Fiber
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Journal Code:F0278A
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ISSN:0037-9875
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VOL.59;NO.3;PAGE.110-114(2003)
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| Figure&Table&Reference;FIG.6, TBL.3, REF.15 |
| Pub. Country;Japan |
| Language;English |
| Abstract;Cyclic compounds such as lactones and N-carboxy .ALPHA. -amino acid anhydrides (NCAs) were graft-polymerized on cellulose dissolved in tetrabutylammomum fluoride / dimethyl suilfoxide (TBAF / DMSO). .EPSILON.-Caprolactone was grafted on cellulose with grafting of 64% in this solvent system. NCAs were also grafted with grafting of over 100%. It is thought that an increase in the nucleophilicity of hydroxyl groups of cellulose by the interaction with TBAF was related to this polymerization. (author abst.) |
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