Biotitization of vermiculite under hydrothermal condition.

Accession number;03A0194738
Title;Biotitization of vermiculite under hydrothermal condition.
Author; MURAKAMI T (Univ. Tokyo, Tokyo, Jpn) KASAMA T (Univ. Tokyo, Tokyo, Jpn) SATO M (Univ. Tokyo, Tokyo, Jpn)
Journal Title;J Mineral Petrol Sci
Journal Code:G0150B
ISSN:1345-6296
VOL.97;NO.6;PAGE.263-268(2002)
Figure&Table&Reference;FIG.8, REF.16
Pub. Country;Japan
Language;English
Abstract;Hydrothermal experiment was carried out reacting vermiculite with K- and Si-bearing solutions in a Teflon vessel at 150.DEG.C. for 14,51, and 71 days to demonstrate biotitization of vermiculite. Our results revealed that biotite is formed within 71 days. High-resolution transmission microscopy and energy dispersive X-ray spectrometry showed that biotite is formed by precipitation directly from solution, domain formation in vermiculite, layer-by-layer transformation of vermiculite, or combination of the three. Our results clearly indicate that biotitization of vermiculite occurs under hydrothermal condition when K is available. Our study suggests that vermiculite formed during weathering is altered progressively to biotite by diagenesis as well as metamorphism after burial. (author abst.)
FULLTEXT