Ion-exchange Reaction of Hydroxyapatites with Eu3+ and Tb3+ Ions

Accession number;03A0636117
Title;Ion-exchange Reaction of Hydroxyapatites with Eu3+ and Tb3+ Ions
Author; KUMADA N (Univ. Yamanashi, Yamanashi, Jpn) IIKUBO N (Univ. Yamanashi, Yamanashi, Jpn) TAKEI T (Univ. Yamanashi, Yamanashi, Jpn) KINOMURA N (Univ. Yamanashi, Yamanashi, Jpn) SUZUKI T (Univ. Yamanashi, Yamanashi, Jpn)
Journal Title;Journal of Ion Exchange
Journal Code:L2416A
ISSN:0915-860X
VOL.14;NO.Supplement;PAGE.153-156(2003)
Figure&Table&Reference;FIG.6, REF.8
Pub. Country;Japan
Language;English
Abstract;Ion-exchange reaction of three types of synthetic hydroxyapatites was attempted with Eu3+ and Tb3+ ions for the purpose of preparing phosphors. The ion-exchange reaction was observed when the concentration of Eu3+ and Tb3+ nitrate solutions was less than 10mmol/dm3, however, in the case of higher concentrated solution hydroxyapatites were dissolved partly to yield EuPO4 H2O and TbPO4 H2O. The emission intensity of the ion-exchanged products depended not only on the uptake amount of Eu3+ and Tb3+ ions but also on the Ca/(P+C) ratio of the starting HAps. (author abst.)