Na-Zeolites Promoted Cannizzaro Reaction of p-Nitrobenzaldehyde in Liquid Phase.
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Accession number;03A0714641
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| Title;Na-Zeolites Promoted Cannizzaro Reaction of p-Nitrobenzaldehyde in Liquid Phase. |
| Author;
OGAWA H
(Tokyo Gakugei Univ., Tokyo, Jpn)
HOSOE T
(Tokyo Gakugei Univ., Tokyo, Jpn)
SENDA H
(Tokyo Gakugei Univ., Tokyo, Jpn)
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Journal Title;Bulletin of Tokyo Gakugei University. Section 4. Mathematics and Natural Sciences
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Journal Code:G0326A
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ISSN:0371-6813
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VOL.55;NO.;PAGE.35-38(2003)
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| Figure&Table&Reference;FIG.2, TBL.3, REF.11 |
| Pub. Country;Japan |
| Language;English |
| Abstract;Zeolites, especially Na-Z-M10 (mordenite type), effectively catalyzed the Cannizzaro reaction by refluxing in DMF solvent where p-nitrobenzaldehyde was converted to p-nitrobenzyl alcohol and p-nitrobenzoic acid by self-oxidation- and-reduction. Activities of catalysts for the reaction have been evaluated by the reaction rate. The higher activity was observed with increase in Na content of the zeolite. Other aromatic aldehydes, o- and m-nitrobenzaldehyde, m- and p-chlorobenzaldehyde, and benzaldehyde, were also converted by this reaction system to their respective products. (author abst.) |
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