Synthesis of Novel Calix[4]arenes Capturing Ionic Guests and Multi-step Regulation of Their Guest Recognition Ability.

Accession number;04A0258593
Title;Synthesis of Novel Calix[4]arenes Capturing Ionic Guests and Multi-step Regulation of Their Guest Recognition Ability.
Author; SAIKI TOSHIYUKI (Univ. of Tsukuba) IWABUCHI JUN (Univ. of Tsukuba) NABESHIMA TATSUYA (Univ. of Tsukuba)
Journal Title;Abstracts. Symposium on Biofunctional Chemistry
Journal Code:L0836A
ISSN:
VOL.18th;NO.;PAGE.20-21(2003)
Figure&Table&Reference;REF.2
Pub. Country;Japan
Language;Japanese
Abstract;A calix[4]arene derivative, which has recognition sites for an alkali metal ion, a transition metal ion, and an anionic guest, was synthesized. The host recognizes Na+, Ag+, and anion simultaneously. The association constant of the host and the anionic guest increases in the presence of Na+ or Ag+. This result clearly shows that multi-step regulation of the recognition of anionic guests is successfully achieved. (author abst.)