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Accession number;04A0258604
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| Title;An Oxidizing Intermediate Generated from a Salen Iron Complex, Related to the Oxygen Activation by Mononuclear Nonheme Iron Enzymes. |
| Author;
KURAHASHI TAKUYA
(Okazakikokuritsukyodokenkyukiko Rikagakuken)
KOBAYASHI YOSHIO
(Okazakikokuritsukyodokenkyukiko Rikagakuken)
NAGATOMO SHIGENORI
(Okazakikokuritsukyodokenkyukiko Rikagakuken)
KITAGAWA TEIZO
(Okazakikokuritsukyodokenkyukiko Rikagakuken)
FUJII HIROSHI
(Okazakikokuritsukyodokenkyukiko Rikagakuken)
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Journal Title;Abstracts. Symposium on Biofunctional Chemistry
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Journal Code:L0836A
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ISSN:
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VOL.18th;NO.;PAGE.42-43(2003)
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| Figure&Table&Reference;FIG.1, REF.3 |
| Pub. Country;Japan |
| Language;Japanese |
| Abstract;An oxidizing intermediate generated from a salen iron complex are investigated as a model of mononuclear nonheme iron enzymes. Addition of mCPBA to the salen iron complex having bulky mesityl substituents in CH2Cl2 at -80.DEG.C. generates the blue-green intermediate. UV-Vis spectra suggest the generation of the transient intermediate having a distinct electronic structure from the starting salen iron complex. The detailed structure is further investigated by means of Moessbauer, EPR, NMR and resonance Raman spectroscopy. (author abst.) |
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