Synthesis and Inclusion Ability of New Cyclodextrin Analogues Incorporating One .BETA.-1,4-Glucosidic Bond.
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Accession number;04A0258615
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| Title;Synthesis and Inclusion Ability of New Cyclodextrin Analogues Incorporating One .BETA.-1,4-Glucosidic Bond. |
| Author;
KIKUZAWA AKIRA
(Osaka Univ., Grad. Sch.)
KIDA TOSHIYUKI
(Osaka Univ., Grad. Sch.)
NAKATSUJI YOJI
(Osaka Univ., Grad. Sch.)
AKASHI MITSURU
(Osaka Univ., Grad. Sch.)
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Journal Title;Abstracts. Symposium on Biofunctional Chemistry
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Journal Code:L0836A
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ISSN:
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VOL.18th;NO.;PAGE.64-65(2003)
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| Figure&Table&Reference;TBL.1, REF.3 |
| Pub. Country;Japan |
| Language;Japanese |
| Abstract;We report here a facile synthesis of new 'skeleton-modified' CDs, in which one .ALPHA.-1,4-glucosidc bond of permethylated .ALPHA.- and .BETA.-CDs is replaced by .BETA.-1,4-glucosidic bond, and their inclusion ability toward aromatic guest compounds. Interestingly, the synthesized host molecules showed inclusion selectivity for the m-isomer over the p-isomer, in contrast to the cases of the permethylated CDs with the p-isomer selectivity. (author abst.) |
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