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Accession number;04A0258618
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| Title;Design of MIII(Schiff base) apo-myoglobin based on the crystal structure. |
| Author;
KOSHIYAMA TOMOMI
(Meidai In)
UENO TAKAFUMI
(Nadai Butsukokuse)
OHASHI MASATAKA
(Graduate Univ. Advances Studies)
KONO MASAHARU
(Meidai In)
KONDO KAZUYOSHI
(Meidai In)
SUZUKI ATSUO
(Meidai In)
YAMANE TAKASHI
(Meidai In)
WATANABE YOSHIHITO
(Meidai In)
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Journal Title;Abstracts. Symposium on Biofunctional Chemistry
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Journal Code:L0836A
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ISSN:
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VOL.18th;NO.;PAGE.72-73(2003)
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| Figure&Table&Reference;FIG.2, TBL.1, REF.3 |
| Pub. Country;Japan |
| Language;Japanese |
| Abstract;Construction of artificial metalloenzymes is one of the most important subjects in bioinorganic chemistry. We have already reported constructed artificial metalloenzymes by noncovalent insertion of a symmetric Cr(III) Schiff base complex, which is known as a oxidation catalyst in organic solvent, into the empty cavity of apo-myoglobin (Mb). To control catalytic reactivity, we have designed Mn(III) Schiff base complex based on the crystal structure. (author abst.) |
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