Epoxidation with an Electrocatalytic P-450 Model System in an Acidic Solution
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Accession number;05A0106831
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| Title;Epoxidation with an Electrocatalytic P-450 Model System in an Acidic Solution |
| Author;
MICHIDA T
(Kobe-gakuin Univ., Kobe, Jpn)
SAIKI C
(Kobe-gakuin Univ., Kobe, Jpn)
YAMASAKI C
(Kobe-gakuin Univ., Kobe, Jpn)
YAMAOKA Y
(Kobe-gakuin Univ., Kobe, Jpn)
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Journal Title;Chem Pharm Bull
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Journal Code:G0504A
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ISSN:0009-2363
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VOL.53;NO.2;PAGE.151-152(2005)
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| Figure&Table&Reference;FIG.1, TBL.1, REF.8 |
| Pub. Country;Japan |
| Language;English |
| Abstract;An electrochemical P-450 model system using meso-tetraphenylporphyrinatomanganese(III) chloride (MnTPP), imidazole and acetic acid was tested in an acetonitrile solution, and epoxide was obtained with a good current efficiency. The results of cyclic voltammetry revealed that acid plays an important role in the second electron transfer. (author abst.) |
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