Inyoite from Fuka, Okayama Prefecture, Japan

Accession number;04A0674187
Title;Inyoite from Fuka, Okayama Prefecture, Japan
Author; KUSACHI I (Okayama Univ., Okayama, Jpn) KOBAYASHI S (Okayama Univ. Sci., Okayama, Jpn) ()
Journal Title;J Mineral Petrol Sci
Journal Code:G0150B
ISSN:1345-6296
VOL.99;NO.2;PAGE.67-71(2004)
Figure&Table&Reference;FIG.4, TBL.3, REF.11
Pub. Country;Japan
Language;English
Abstract;Inyoite was found as fissure fillings in calcium borate minerals, which occur as an irregularly shaped body in the crystalline limestone near the gehlenite-spurrite skarns at the Fuka mine, Okayama Prefecture, Japan. Inyoite occurs as aggregates of tabular crystals up to 1mm wide, and rarely as euhedral crystals up to 0.5mm wide in fissures of calcium borate minerals such as nifontovite, pentahydroborite, sibirskite and parasibirskite. The fissure fillings are composed only of inyoite. This is the first finding of inyoite in Japan. The type of occurrence is also different from those in many other localities in the world. Electron microprobe and CHNS/O analyses gave the empirical formula Ca1.99B5.96O5.92(OH)10 8.08H2O on the basis of O=24. The unit cell parameters are a=10.616(2), b=12.068(1), c=8.404(1).ANGS. and .BETA.=114.01(1).DEG.. The mineral is optically biaxial negative with refractive indices .ALPHA.=1.492, .BETA.=1.506 and .GAMMA.=1.517, giving a calculated 2V=82.DEG.. The Vickers microhardness is 91kg mm-2 (10g load) and the Mohs hardness number is 2.5. The measured density is 1.875g cm-3. It is likely that the inyoite at the Fuka mine was formed by a reaction of ground water with calcium borate minerals at a temperature of around 20.DEG.C.. (author abst.)
FULLTEXT