Iridoid Glucosides from the Aerial Parts of Globularia alypum L. (Globulariaceae)
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Accession number;06A0025405
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| Title;Iridoid Glucosides from the Aerial Parts of Globularia alypum L. (Globulariaceae) |
| Author;
ES-SAFI NOUR-EDDINE
(Unite De Phytopharmacie Et Mediateurs Chimiques, Inra)
ES-SAFI NOUR-EDDINE
(Lab. De Chimie Organique Et D'etudes Physico-chimiques, Ecole Normale Superieure)
KHLIFI SAMIRA
(Lab. De Biochimie Appliquee Et Biotechnologie, Fac. Des Sciences)
KOLLMANN ALBERT
(Unite De Phytopharmacie Et Mediateurs Chimiques, Inra)
KERHOAS LUCIEN
(Unite De Phytopharmacie Et Mediateurs Chimiques, Inra)
EL ABBOUYI AHMED
(Lab. De Biochimie Appliquee Et Biotechnologie, Fac. Des Sciences)
DUCROT PAUL-HENRI
(Unite De Phytopharmacie Et Mediateurs Chimiques, Inra)
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Journal Title;Chem Pharm Bull
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Journal Code:G0504A
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ISSN:0009-2363
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VOL.54;NO.1;PAGE.85-88 (J-STAGE)(2006)
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| Figure&Table&Reference;FIG.3, TBL.1, REF.25 |
| Pub. Country;Japan |
| Language;English |
| Abstract;From the hydromethanolic extract of the aerial parts of Globularia alypum grown in Morocco, a new chlorinated iridoid glucoside, globularioside has been isolated beside 5 known iridoid glycosides, globularin, globularicisin, globularidin, globularinin and globularimin. This is the first report of a chlorinated iridoid in G. alypum and in the Globulareaceae. Unlike all other known 7-chlorinated iridoid glucosides where the chlorine atom exhibits an .ALPHA. configuration, globularioside incorporate the chlorine atom as a 7.BETA. substituent. The structures of the isolated compounds were established on the basis of ESI-MS, MS-MS, 1D and 2D NMR spectral analysis. (Author abst.) |
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