Four New Cycloartane Glycosides from Thalictrum fortunei
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Accession number;06A0025410
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| Title;Four New Cycloartane Glycosides from Thalictrum fortunei |
| Author;
ZHANG XIAN-TAO
(Dep. Of Phytochemistry, China Pharmaceutical Univ.)
ZHANG LEI-HONG
(Dep. Of Phytochemistry, China Pharmaceutical Univ.)
YE WEN-CAI
(Dep. Of Phytochemistry, China Pharmaceutical Univ.)
YE WEN-CAI
(Inst. Of Traditional Chinese Medicine And Natural Products, Jinan Univ.)
ZHANG XIAO-LING
(Dep. Of Phytochemistry, Jiangsu Univ.)
YIN ZHI-QI
(Dep. Of Phytochemistry, China Pharmaceutical Univ.)
ZHAO SHOU-XUN
(Dep. Of Phytochemistry, China Pharmaceutical Univ.)
YAO XIN-SHENG
(Inst. Of Traditional Chinese Medicine And Natural Products, Jinan Univ.)
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Journal Title;Chem Pharm Bull
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Journal Code:G0504A
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ISSN:0009-2363
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VOL.54;NO.1;PAGE.107-110 (J-STAGE)(2006)
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| Figure&Table&Reference;FIG.1, TBL.2, REF.10 |
| Pub. Country;Japan |
| Language;English |
| Abstract;Four new cycloartane glycosides were isolated from the aerial parts of Thalictrum fortunei (Ranunculaceae). The chemical structures of these new glycosides were elucidated as 3-O-.BETA.-D-glucopyranosyl-(1.RAR.4)-.BETA.-D-fucopyranosyl (22S,24Z)-cycloart-24-en-3.BETA.,22,26-triol 26-O-.BETA.-D-glucopyranoside, 3-O-.BETA.-D-glucopyranosyl-(1.RAR.4)-.BETA.-D-fucopyranosyl (22S,24Z)-cycloart-24-en-3.BETA.,22,26-triol 26-O-.BETA.-D-quinovopyranosyl-(1.RAR.6)-.BETA.-D-glucopyranoside, 3-O-.BETA.-D-glucopyranosyl-(1.RAR.4)-.BETA.-D-fucopyranosyl (22S,24Z)-cycloart-24-en-3.BETA.,22,26-triol 26-O-.BETA.-D-xylopyranosyl-(1.RAR.6)-.BETA.-D-glucopyranoside, and 3-O-.BETA.-D-glucopyranosyl-(1.RAR.4)-.BETA.-D-fucopyranosyl (22S,24Z)-cycloart-24-en-3.BETA.,22,26-triol 26-O-.ALPHA.-L-arabinopyranosyl-(1.RAR.6)-.BETA.-D-glucopyranoside by extensive NMR methods, HR-ESI-MS, and hydrolysis. This is the first report of (22S,24Z)-3.BETA.,22,26-trihydroxycycloartan-24-ene (thelictogenin A, 5) being glycosylated at C-26. (Author abst.) |
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