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Accession number;06A0107332
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| Title;Novel Diels-Alder Reaction of 4-Nitro-1(2H)-isoquinolones |
| Author;
FUJITA REIKO
(Tohoku Pharmaceutical Univ.)
WAKAYANAGI SOTA
(Tohoku Pharmaceutical Univ.)
WAKAMATSU HIDEAKI
(Tohoku Pharmaceutical Univ.)
MATSUZAKI HISAO
(Tohoku Pharmaceutical Univ.)
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Journal Title;Chem Pharm Bull
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Journal Code:G0504A
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ISSN:0009-2363
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VOL.54;NO.2;PAGE.209-212 (J-STAGE)(2006)
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| Figure&Table&Reference;FIG.1, TBL.2, REF.15 |
| Pub. Country;Japan |
| Language;English |
| Abstract;A novel Diels-Alder (DA) reaction with 4-nitro-1(2H)-isoquinolones acting as the dienophile afforded 5(6H)-phenanthridone derivatives. The DA reaction of 4-nitro-1(2H)-isoquinolone with 1-methoxy-1,3-butadiene gave biologically active 5(6H)-phenanthridone possessing in a high yield. Regioselectivity of 4-nitro-1(2H)-isoquinolones with 1-methoxy-3-silyloxy-1,3-butadiene was calculated using molecular orbital (MO) calculations. (Author abst.) |
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