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Accession number;06A0548457
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| Title;Structures of Endohedral Metallofullerenes |
| Author;
AKASAKA TAKESHI
(Univ. of Tsukuba)
NAGASE SHIGERU
(Bunshikagakuken)
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Journal Title;Journal of the Crystallographic Society of Japan
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Journal Code:G0232A
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ISSN:0369-4585
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VOL.48;NO.3;PAGE.230-235(2006)
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| Figure&Table&Reference;FIG.9, TBL.1, REF.46 |
| Pub. Country;Japan |
| Language;Japanese |
| Abstract;The structures of many typical endohedral metallofullerenes have been reported by the powder X-ray analysis. For example, the report of the trimetallofullerene Sc3C82 has shown that the endohedral structure is Sc3@C82, this being widely accepted. However, the recent '13'C NMR spectroscopy and X-ray single crystal analysis have revealed that the structure of Sc3C82 is not Sc3@C82 but Sc3C2@C80. This may suggest that the endohedral structures reported from the powder X-ray study are not always reliable even in a qualitative sense. (author abst.) |
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